#  CVTZ  EMSL  Basis Set Exchange Library  3/15/13 10:17 AM
# Elements                             References
# --------                             ----------
# Li Be Na Mg K Ca : M. A. Iron, M. Oren, J. M. L. Martin, Alkali and Alkaline Earth Metal Compounds : Core-Valence Basis Sets and Importance of Subvalence, Mol. Phys. 101, 1345 (2003).
# 



basis "Li_CVTZ" SPHERICAL
Li    S
      0.59880000E+04         0.13300000E-03   
      0.89890000E+03         0.10250000E-02   
      0.20590000E+03         0.52720000E-02   
      0.59240000E+02         0.20929000E-01   
      0.19870000E+02         0.66340000E-01   
      0.74060000E+01         0.16577500E+00   
      0.29300000E+01         0.31503800E+00   
      0.11890000E+01         0.39352300E+00   
      0.47980000E+00         0.19087000E+00   
      0.75090000E-01         0.54140000E-02   
      0.28320000E-01        -0.13280000E-02   
Li    S
      0.59880000E+04        -0.21000000E-04   
      0.89890000E+03        -0.16100000E-03   
      0.20590000E+03        -0.82000000E-03   
      0.59240000E+02        -0.33260000E-02   
      0.19870000E+02        -0.10519000E-01   
      0.74060000E+01        -0.28097000E-01   
      0.29300000E+01        -0.55936000E-01   
      0.11890000E+01        -0.99237000E-01   
      0.47980000E+00        -0.11218900E+00   
      0.75090000E-01         0.56788900E+00   
      0.28320000E-01         0.53038200E+00   
Li    S
      0.75090000E-01         1.0000000        
Li    S
      0.28320000E-01         1.0000000        
Li    S
      1.6623733541           1.0000000        
Li    S
      4.9087410257           1.0000000        
Li    P
      0.32660000E+01         0.86300000E-02   
      0.65110000E+00         0.47538000E-01   
      0.16960000E+00         0.20977200E+00   
      0.55780000E-01         0.52852200E+00   
      0.20500000E-01         0.38274400E+00   
Li    P
      0.55780000E-01         1.0000000        
Li    P
      0.20500000E-01         1.0000000        
Li    P
      1.9801361590           1.0000000        
Li    P
      7.7374111536           1.0000000        
Li    D
      0.18740000E+00         1.0000000        
Li    D
      0.80100000E-01         1.0000000        
Li    D
      4.8814932277           1.0000000        
Li    F
      0.18290000E+00         1.0000000        
end
basis "Be_CVTZ" SPHERICAL
Be    S
      0.68630000E+04         0.23603569E-03   
      0.10300000E+04         0.18264478E-02   
      0.23470000E+03         0.94516046E-02   
      0.66560000E+02         0.37956905E-01   
      0.21690000E+02         0.11996483E+00   
      0.77340000E+01         0.28216178E+00   
      0.29160000E+01         0.42740399E+00   
      0.11300000E+01         0.26627800E+00   
      0.25770000E+00         0.18193015E-01   
      0.11010000E+00        -0.72751949E-02   
      0.44090000E-01         0.19032814E-02   
Be    S
      0.68630000E+04        -0.43079899E-04   
      0.10300000E+04        -0.33255552E-03   
      0.23470000E+03        -0.17361462E-02   
      0.66560000E+02        -0.70117525E-02   
      0.21690000E+02        -0.23125620E-01   
      0.77340000E+01        -0.58137619E-01   
      0.29160000E+01        -0.11455592E+00   
      0.11300000E+01        -0.13590810E+00   
      0.25770000E+00         0.22802609E+00   
      0.11010000E+00         0.57744067E+00   
      0.44090000E-01         0.31787332E+00   
Be    S
      0.25770000E+00         1.0000000        
Be    S
      0.44090000E-01         1.0000000        
Be    S
      1.6452178654           1.0000000        
Be    S
      4.7235314402           1.0000000        
Be    P
      0.74360000E+01         0.10736034E-01   
      0.15770000E+01         0.62853547E-01   
      0.43520000E+00         0.24817977E+00   
      0.14380000E+00         0.52369883E+00   
      0.49940000E-01         0.35342527E+00   
Be    P
      0.14380000E+00         1.0000000        
Be    P
      0.49940000E-01         1.0000000        
Be    P
      3.7976623259           1.0000000        
Be    P
     14.5493526003           1.0000000        
Be    D
      0.34800000E+00         1.0000000        
Be    D
      0.18030000E+00         1.0000000        
Be    D
      9.1830456548           1.0000000        
Be    F
      0.32500000E+00         1.0000000        
end
basis "Na_CVTZ" SPHERICAL
Na    S
      0.42300000E+06         0.18061800E-04   
      0.63340000E+05         0.14043000E-03   
      0.14410000E+05         0.73843800E-03   
      0.40770000E+04         0.31118200E-02   
      0.13280000E+04         0.11208100E-01   
      0.47860000E+03         0.35282800E-01   
      0.18620000E+03         0.95989700E-01   
      0.76920000E+02         0.21373500E+00   
      0.33320000E+02         0.34868800E+00   
      0.15000000E+02         0.32456600E+00   
      0.68690000E+01         0.11263300E+00   
      0.26830000E+01         0.70679700E-02   
      0.11090000E+01         0.59801000E-03   
      0.45400000E+00         0.20413000E-03   
      0.60150000E-01        -0.53087000E-05   
      0.23820000E-01         0.18260500E-05   
Na    S
      0.42300000E+06        -0.44065300E-05   
      0.63340000E+05        -0.34344300E-04   
      0.14410000E+05        -0.18011400E-03   
      0.40770000E+04        -0.76390000E-03   
      0.13280000E+04        -0.27524800E-02   
      0.47860000E+03        -0.88601600E-02   
      0.18620000E+03        -0.24793900E-01   
      0.76920000E+02        -0.60599500E-01   
      0.33320000E+02        -0.11644600E+00   
      0.15000000E+02        -0.16243700E+00   
      0.68690000E+01        -0.43889100E-01   
      0.26830000E+01         0.33791700E+00   
      0.11090000E+01         0.56134700E+00   
      0.45400000E+00         0.24524000E+00   
      0.60150000E-01         0.40675400E-02   
      0.23820000E-01        -0.12674600E-02   
Na    S
      0.42300000E+06         0.66301900E-06   
      0.63340000E+05         0.51576900E-05   
      0.14410000E+05         0.27125000E-04   
      0.40770000E+04         0.11463500E-03   
      0.13280000E+04         0.41511800E-03   
      0.47860000E+03         0.13297800E-02   
      0.18620000E+03         0.37559500E-02   
      0.76920000E+02         0.91402500E-02   
      0.33320000E+02         0.17985900E-01   
      0.15000000E+02         0.25147700E-01   
      0.68690000E+01         0.76352200E-02   
      0.26830000E+01        -0.61458900E-01   
      0.11090000E+01        -0.11572100E+00   
      0.45400000E+00        -0.15890600E+00   
      0.60150000E-01         0.62640600E+00   
      0.23820000E-01         0.47540200E+00   
Na    S
      0.45400000E+00         1.0000000        
Na    S
      0.23820000E-01         1.0000000        
Na    S
      0.9727005242           1.0000000        
Na    S
      4.8679536692           1.0000000        
Na    P
      0.24330000E+03         0.22439200E-02   
      0.57390000E+02         0.17399700E-01   
      0.18100000E+02         0.77412500E-01   
      0.65750000E+01         0.21910200E+00   
      0.25210000E+01         0.37852200E+00   
      0.96070000E+00         0.39490200E+00   
      0.35120000E+00         0.16042400E+00   
      0.98270000E-01         0.23331100E-02   
      0.37340000E-01         0.19953600E-02   
      0.15000000E-01        -0.77734400E-03   
Na    P
      0.24330000E+03        -0.22240100E-03   
      0.57390000E+02        -0.17427700E-02   
      0.18100000E+02        -0.77545600E-02   
      0.65750000E+01        -0.22518700E-01   
      0.25210000E+01        -0.38433000E-01   
      0.96070000E+00        -0.45017700E-01   
      0.35120000E+00        -0.19213200E-01   
      0.98270000E-01         0.18269700E+00   
      0.37340000E-01         0.55789700E+00   
      0.15000000E-01         0.37302200E+00   
Na    P
      0.37340000E-01         1.0000000        
Na    P
      0.15000000E-01         1.0000000        
Na    P
      0.6447590117           1.0000000        
Na    P
      1.9533692330           1.0000000        
Na    D
      0.13670000E+00         1.0000000        
Na    D
      0.63600000E-01         1.0000000        
Na    D
      1.6002329770           1.0000000        
Na    D
      5.4055870011           1.0000000        
Na    F
      0.13970000E+00         1.0000000        
Na    F
      3.4309079349           1.0000000        
end
basis "Mg_CVTZ" SPHERICAL
Mg    S
      0.16490000E+06         0.72992852E-04   
      0.24710000E+05         0.56665208E-03   
      0.56280000E+04         0.29626934E-02   
      0.15960000E+04         0.12296244E-01   
      0.52100000E+03         0.42732390E-01   
      0.18800000E+03         0.12301339E+00   
      0.73010000E+02         0.27483212E+00   
      0.29900000E+02         0.40181847E+00   
      0.12540000E+02         0.26469734E+00   
      0.43060000E+01         0.33261243E-01   
      0.18260000E+01        -0.44133529E-02   
      0.74170000E+00         0.20602406E-02   
      0.14570000E+00        -0.83847033E-03   
      0.76120000E-01         0.70819497E-03   
      0.33100000E-01        -0.20060176E-03   
Mg    S
      0.16490000E+06        -0.18424833E-04   
      0.24710000E+05        -0.14350020E-03   
      0.56280000E+04        -0.74871024E-03   
      0.15960000E+04        -0.31440747E-02   
      0.52100000E+03        -0.11048121E-01   
      0.18800000E+03        -0.33605846E-01   
      0.73010000E+02        -0.82594554E-01   
      0.29900000E+02        -0.15931351E+00   
      0.12540000E+02        -0.15288784E+00   
      0.43060000E+01         0.19084949E+00   
      0.18260000E+01         0.57996406E+00   
      0.74170000E+00         0.37202938E+00   
      0.14570000E+00         0.21169123E-01   
      0.76120000E-01        -0.11934365E-01   
      0.33100000E-01         0.27732867E-02   
Mg    S
      0.16490000E+06         0.35517561E-05   
      0.24710000E+05         0.27642017E-04   
      0.56280000E+04         0.14440388E-03   
      0.15960000E+04         0.60574423E-03   
      0.52100000E+03         0.21352674E-02   
      0.18800000E+03         0.64993445E-02   
      0.73010000E+02         0.16144594E-01   
      0.29900000E+02         0.31576557E-01   
      0.12540000E+02         0.31637441E-01   
      0.43060000E+01        -0.43914029E-01   
      0.18260000E+01        -0.15109333E+00   
      0.74170000E+00        -0.21766839E+00   
      0.14570000E+00         0.25980682E+00   
      0.76120000E-01         0.54724537E+00   
      0.33100000E-01         0.32590951E+00   
Mg    S
      0.14570000E+00         1.0000000        
Mg    S
      0.33100000E-01         1.0000000        
Mg    S
      0.9205872712           1.0000000        
Mg    S
      5.7787885890           1.0000000        
Mg    P
      0.31690000E+03         0.20753175E-02   
      0.74860000E+02         0.16286888E-01   
      0.23720000E+02         0.73869726E-01   
      0.86690000E+01         0.21429700E+00   
      0.33630000E+01         0.38215378E+00   
      0.13100000E+01         0.39817821E+00   
      0.49110000E+00         0.15287777E+00   
      0.23640000E+00        -0.43753955E-02   
      0.87330000E-01         0.62958244E-02   
      0.32370000E-01        -0.15676869E-02   
Mg    P
      0.31690000E+03        -0.32972687E-03   
      0.74860000E+02        -0.25875416E-02   
      0.23720000E+02        -0.11912032E-01   
      0.86690000E+01        -0.35022673E-01   
      0.33630000E+01        -0.63996825E-01   
      0.13100000E+01        -0.70443568E-01   
      0.49110000E+00        -0.37583553E-01   
      0.23640000E+00         0.17704345E+00   
      0.87330000E-01         0.56670743E+00   
      0.32370000E-01         0.39614295E+00   
Mg    P
      0.87330000E-01         1.0000000        
Mg    P
      0.32370000E-01         1.0000000        
Mg    P
      1.0535210745           1.0000000        
Mg    P
      3.0364235255           1.0000000        
Mg    D
      0.29400000E+00         1.0000000        
Mg    D
      0.12600000E+00         1.0000000        
Mg    D
      2.1460271700           1.0000000        
Mg    D
      7.0378303861           1.0000000        
Mg    F
      0.25200000E+00         1.0000000        
Mg    F
      4.4855713424           1.0000000        
end
basis "K_CVTZ" SPHERICAL
K    S
      0.1909345665E-01      -0.00000170819    
      0.4899385705E-01       0.00000699165    
      0.1182168340E+00      -0.00001809213    
      0.2707202135E+00       0.00003117837    
      0.5938663979E+00      -0.00010344594    
      0.1259524369E+01       0.00008710641    
      0.2606736858E+01      -0.00016757678    
      0.5313536284E+01       0.00125808438    
      0.1076685816E+02       0.00913591060    
      0.2188952107E+02       0.10895583344    
      0.4506594658E+02       0.30039305255    
      0.9483065478E+02       0.33537488908    
      0.2058543544E+03       0.22119256766    
      0.4652704464E+03       0.10854981691    
      0.1105116392E+04       0.04410869165    
      0.2784138023E+04       0.01568328689    
      0.7508907135E+04       0.00498550345    
      0.2188209905E+05       0.00142662090    
      0.6954253913E+05       0.00036398591    
      0.2432677111E+06       0.00008331461    
      0.9453960843E+06       0.00001580589    
      0.4119661925E+07       0.00000344355    
K    S
      0.1909345665E-01       0.00007476174    
      0.4899385705E-01      -0.00030556558    
      0.1182168340E+00       0.00077725159    
      0.2707202135E+00      -0.00103645061    
      0.5938663979E+00       0.00486619689    
      0.1259524369E+01       0.02612372005    
      0.2606736858E+01       0.30358239386    
      0.5313536284E+01       0.55962134674    
      0.1076685816E+02       0.27423535789    
      0.2188952107E+02      -0.06055290481    
      0.4506594658E+02      -0.17786036037    
      0.9483065478E+02      -0.14013397379    
      0.2058543544E+03      -0.07577920879    
      0.4652704464E+03      -0.03378770768    
      0.1105116392E+04      -0.01310950419    
      0.2784138023E+04      -0.00456764015    
      0.7508907135E+04      -0.00143919283    
      0.2188209905E+05      -0.00041054334    
      0.6954253913E+05      -0.00010460045    
      0.2432677111E+06      -0.00002393715    
      0.9453960843E+06      -0.00000453996    
      0.4119661925E+07      -0.00000098919    
K    S
      0.1909345665E-01      -0.00052118030    
      0.4899385705E-01       0.00314756221    
      0.1182168340E+00       0.01579361240    
      0.2707202135E+00       0.36924562377    
      0.5938663979E+00       0.65572135783    
      0.1259524369E+01       0.23865097576    
      0.2606736858E+01      -0.29678753570    
      0.5313536284E+01      -0.33875730699    
      0.1076685816E+02      -0.11351151923    
      0.2188952107E+02       0.02158282957    
      0.4506594658E+02       0.06396961857    
      0.9483065478E+02       0.04785489531    
      0.2058543544E+03       0.02549313002    
      0.4652704464E+03       0.01120366429    
      0.1105116392E+04       0.00434164416    
      0.2784138023E+04       0.00150532894    
      0.7508907135E+04       0.00047501650    
      0.2188209905E+05       0.00013518086    
      0.6954253913E+05       0.00003450013    
      0.2432677111E+06       0.00000788201    
      0.9453960843E+06       0.00000149716    
      0.4119661925E+07       0.00000032581    
K    S
      0.1909345665E-01       0.63278989642    
      0.4899385705E-01       0.57795131641    
      0.1182168340E+00      -0.13209250671    
      0.2707202135E+00      -0.19781896078    
      0.5938663979E+00      -0.17460607725    
      0.1259524369E+01      -0.05816470700    
      0.2606736858E+01       0.06256403459    
      0.5313536284E+01       0.07079819436    
      0.1076685816E+02       0.02217278529    
      0.2188952107E+02      -0.00407782912    
      0.4506594658E+02      -0.01252150751    
      0.9483065478E+02      -0.00925645546    
      0.2058543544E+03      -0.00494138378    
      0.4652704464E+03      -0.00216266685    
      0.1105116392E+04      -0.00083966852    
      0.2784138023E+04      -0.00029049645    
      0.7508907135E+04      -0.00009181052    
      0.2188209905E+05      -0.00002608961    
      0.6954253913E+05      -0.00000666671    
      0.2432677111E+06      -0.00000152138    
      0.9453960843E+06      -0.00000028928    
      0.4119661925E+07      -0.00000006290    
K    S
      0.0181486651           1.0000000        
K    S
      0.0507479214           1.0000000        
K    S
      0.3458959019           1.0000000        
K    S
      1.7791738252           1.0000000        
K    P
      0.1288263088E+00       0.00000693267    
      0.3027945265E+00       0.00004960813    
      0.6624491061E+00       0.00134037127    
      0.1375023171E+01       0.02436951461    
      0.2760021556E+01       0.15954505194    
      0.5460744403E+01       0.32823122847    
      0.1085475691E+02       0.32552542139    
      0.2209577254E+02       0.21419159673    
      0.4694734906E+02       0.10139861629    
      0.1061250022E+03       0.03555596279    
      0.2601483426E+03       0.00970633659    
      0.7048765891E+03       0.00205833615    
      0.2151719924E+04       0.00033225264    
      0.7542772099E+04       0.00004748204    
K    P
      0.1288263088E+00       0.07915000431    
      0.3027945265E+00       0.35739406322    
      0.6624491061E+00       0.44624869562    
      0.1375023171E+01       0.25495277653    
      0.2760021556E+01       0.00178930522    
      0.5460744403E+01      -0.12045436198    
      0.1085475691E+02      -0.11074433452    
      0.2209577254E+02      -0.07045838348    
      0.4694734906E+02      -0.03220155813    
      0.1061250022E+03      -0.01105836632    
      0.2601483426E+03      -0.00297653829    
      0.7048765891E+03      -0.00062963218    
      0.2151719924E+04      -0.00010111782    
      0.7542772099E+04      -0.00001449018    
K    P
      0.0275233530           1.0000000        
K    P
      0.0598342601           1.0000000        
K    P
      0.2236708155           1.0000000        
K    P
      0.5294791856           1.0000000        
K    P
      2.5987944798           1.0000000        
K    D
      0.0598916844           1.0000000        
K    D
      0.4311105955           1.0000000        
K    D
      1.0358684196           1.0000000        
K    D
      2.5856768395           1.0000000        
K    F
      0.0887804601           1.0000000        
K    F
      1.1289185352           1.0000000        
end
basis "Ca_CVTZ" SPHERICAL
Ca    S
      0.0254108441803       -0.00000238       
      0.0630307004441        0.00000950       
      0.1478138859055       -0.00002436       
      0.3306287416437        0.00004424       
      0.7116401635679       -0.00012829       
      1.4869863512959        0.00011531       
      3.0430732505456       -0.00021688       
      6.1533119329301        0.00132105       
     12.4030577392801        0.01054215       
     25.1422485957806        0.11698026       
     51.7091253452967        0.30641477       
    108.8554557050285        0.33226934       
    236.6384704702638        0.21552371       
    535.9260256533751        0.10463039       
   1275.6775212307653        0.04219866       
   3219.7764745844952        0.01492711       
   8693.4370914503652        0.00472921       
  25332.0589264397786        0.00135120       
  80370.1635951880162        0.00034488       
 280089.4895136958221        0.00007922       
 1081704.3511574361473       0.00001509       
 4670489.0073897046968       0.00000334       
Ca    S
      0.0254108441803        0.00007752       
      0.0630307004441       -0.00030441       
      0.1478138859055        0.00076909       
      0.3306287416437       -0.00103646       
      0.7116401635679        0.00490140       
      1.4869863512959        0.03080040       
      3.0430732505456        0.31571028       
      6.1533119329301        0.55947885       
     12.4030577392801        0.26191142       
     25.1422485957806       -0.07091442       
     51.7091253452967       -0.18042054       
    108.8554557050285       -0.13893101       
    236.6384704702638       -0.07425808       
    535.9260256533751       -0.03283320       
   1275.6775212307653       -0.01265980       
   3219.7764745844952       -0.00439118       
   8693.4370914503652       -0.00137934       
  25332.0589264397786       -0.00039292       
  80370.1635951880162       -0.00010015       
 280089.4895136958221       -0.00002300       
 1081704.3511574361473      -0.00000438       
 4670489.0073897046968      -0.00000097       
Ca    S
      0.0254108441803       -0.00103986       
      0.0630307004441        0.00382724       
      0.1478138859055        0.00781953       
      0.3306287416437        0.35108906       
      0.7116401635679        0.69072014       
      1.4869863512959        0.24098390       
      3.0430732505456       -0.31815625       
      6.1533119329301       -0.35516646       
     12.4030577392801       -0.11408178       
     25.1422485957806        0.02693817       
     51.7091253452967        0.06789572       
    108.8554557050285        0.04968204       
    236.6384704702638        0.02613839       
    535.9260256533751        0.01139580       
   1275.6775212307653        0.00438697       
   3219.7764745844952        0.00151463       
   8693.4370914503652        0.00047638       
  25332.0589264397786        0.00013540       
  80370.1635951880162        0.00003457       
 280089.4895136958221        0.00000793       
 1081704.3511574361473       0.00000151       
 4670489.0073897046968       0.00000033       
Ca    S
      0.0254108441803        0.47080628       
      0.0630307004441        0.67540427       
      0.1478138859055        0.04170744       
      0.3306287416437       -0.28604603       
      0.7116401635679       -0.24547194       
      1.4869863512959       -0.07383289       
      3.0430732505456        0.08460201       
      6.1533119329301        0.09257505       
     12.4030577392801        0.02777254       
     25.1422485957806       -0.00640491       
     51.7091253452967       -0.01642939       
    108.8554557050285       -0.01189845       
    236.6384704702638       -0.00626256       
    535.9260256533751       -0.00272107       
   1275.6775212307653       -0.00104869       
   3219.7764745844952       -0.00036147       
   8693.4370914503652       -0.00011381       
  25332.0589264397786       -0.00003231       
  80370.1635951880162       -0.00000826       
 280089.4895136958221       -0.00000189       
 1081704.3511574361473      -0.00000036       
 4670489.0073897046968      -0.00000008       
Ca    S
      0.0254108441803        1.0000000        
Ca    S
      0.1478138859055        1.0000000        
Ca    S
      0.4499982319           1.0000000        
Ca    S
      2.2508513755           1.0000000        
Ca    P
      0.1665324969063       -0.00003826       
      0.3898123762486        0.00012743       
      0.8418804590783        0.00155932       
      1.7137398379361        0.03118418       
      3.3589264581687        0.16965296       
      6.4755806892356        0.32235891       
     12.5441444458114        0.31424060       
     24.9430155826533        0.20943205       
     52.0072555417719        0.10189743       
    116.1575552830732        0.03677056       
    283.8971415897409        0.01019832       
    775.6505211145972        0.00215675       
   2420.0489531403118        0.00033968       
   8808.3931189963077        0.00004516       
Ca    P
      0.1665324969063        0.06916953       
      0.3898123762486        0.35734702       
      0.8418804590783        0.46622777       
      1.7137398379361        0.24354336       
      3.3589264581687       -0.00907722       
      6.4755806892356       -0.12729362       
     12.5441444458114       -0.11455950       
     24.9430155826533       -0.07397203       
     52.0072555417719       -0.03464363       
    116.1575552830732       -0.01224615       
    283.8971415897409       -0.00334268       
    775.6505211145972       -0.00070550       
   2420.0489531403118       -0.00011042       
   8808.3931189963077       -0.00001474       
Ca    P
      0.1665324969063        1.0000000        
Ca    P
      0.3898123762486        1.0000000        
Ca    P
      0.0559602444           1.0000000        
Ca    P
      0.8189608854           1.0000000        
Ca    P
      3.7602627099           1.0000000        
Ca    D
      0.0822549022           1.0000000        
Ca    D
      0.2124268180           1.0000000        
Ca    D
      0.7946174299           1.0000000        
Ca    D
      2.1468368570           1.0000000        
Ca    F
      0.1474011780           1.0000000        
Ca    F
      1.3868465157           1.0000000        
end
